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Alcohol Reactions. The functional group of the alcohols is the hydroxyl group, –OH.Unlike the alkyl halides, this group has two reactive covalent bonds, the C–O bond and the O–H bond. The electronegativity of oxygen is substantially greater than that of carbon and hydrogen.
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Both alcohols will burn with a fairly clean, blue flame. C 2 H 5 OH + 3O 2 → 2CO 2 + 3H 2 O C 3 H 7 OH + 4½O 2 → 3CO 2 + 4H 2 O. Both alcohols will fizz with sodium to form hydrogen. C 2 H 5 OH + Na → C 2 H 5 ONa (sodium ethoxide) + ½H 2 C 3 H 7 OH + Na → C 3 H 7 ONa (sodium propoxide) + ½H 2. Both alcohols are oxidised to aldehydes ...
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